FACT - FLUTe Activated Carbon Technique

The FACT is an innovative method developed by FLUTe for mapping the dissolved phase contaminant distribution in a sealed borehole with 6" to 3' resolution.

Liner with Activated Carbon felt to detect NAPL

Figure 1. FACT Construction, with the FACT stitched between the NAPL FLUTe cover (striped) and a diffusion barrier (silver).

Scatter plot for trichloroethylene detection using liner

Figure 2. FACT results for TCE on a 6" scale. 

How the System Works: The FACT is a 1.5" contunous strip of activated carbon felt that is added to the NAPL FLUTe and emplaced against the borehole wall during the eversion of a blank liner or installation through GeoProbe rods (for overburden applications). Once positioned against the borehole wall, the FACT wicks by diffusion, contaminants in pore spaces and fracture flows. As the diffusion process takes place in a sealed borehole, the concentrations recorded by the FACT are not influenced by cross contamination and/or leakage issues often associated with packer-based characterization. After 2 weeks, the FACT is removed from the well, cut into the desired sample intervals (6" to 3') and sent to the lab for analysis (EPA 8265).

The pressure exerted by the liner on the borehole wall (generally 5 to 10 feet of water pressure) creates a strong seal which prevents preferential flows from developing. Concerns of influence by contact with borehole water are put to rest from the protection provided by the hydrophobic NAPL FLUTe cover and very fast installation and removal procedures. This minimizes interval exposure times (a few seconds). As a precaution, the borehole water is usually pumped from the hole as the liner is everted.

FACT Results: The FACT measurements are very representative and therefore show where the true contaminant peaks are located at depth. The replica contaminant distribution can be used along with FLUTe Transmissivity Profiling data to design a multi-level groundwater sampling system and fate/transport CSM.

Borehole transmissivity over depth using FACT
trichloroethylene detection in sedimentary rock graphusing FACT
VOC detection graph using FACT

Figure 3: Transmissivity Profile and FACT data. Note the high TCE concentrations at 112' and 140' BGS in very low transmissive fractures compared to low TCE concentrations in high flowing fractures at 90' and 130'. The TCE concentrations at 140' and 112' are the same or twice as high, respectively, as the highest flowing fracture in the borehole at 130' despite the fact that they are two of the lowest flowing fractures in the borehole. This data emphasizes the need for high resolution methods rather than coarse measurements to assure that all significant contaminant source zones are properly identified during characterization. Water Samples (green diamonds), validate the FACT concentrations. 

Click Here for the FACT Method for a Continuous Contaminant Profile Presentation - NGWA October 2017

TECHNICAL NOTES:

Installation Times:

 

FLUTe liner systems should be installed as quickly as possible after the hole is drilled to minimize cross connection effects of the borehole water on the pore water in the open borehole.

Reaction Times:

Vadose Zone: The FACT is typically left in place for 48 hours for a vadose zone installation to allow the diffusion process from the formation into the carbon.

Saturated Zone: The FACT should be left in place in the saturated zone for about two weeks due to the diffusion coefficient being much smaller in water than in air. A diffusion calculation shows that two days is long enough to "see" about 0.5cm into the borehole wall with 7% porosity. Concentration in pores is 2,700 ug/L. That improves after 2 weeks.

Academic Analysis of the FACT: A master's thesis is available by Monique Beyer of the Danish Technical University which is a rigorous assessment of the FACT analysis method and its use for a fractured rock site.

FLUTe Activated Carbon Technique